The Group B of the 1999 Copa América was one of the three groups of competing nations in the 1999 Copa América. It comprised Brazil, Chile, Venezuela, and Mexico. Group play began on June 30 and ended on July 6.

Brazil won the group and faced Argentina, the runner-up of Group C, in the quarterfinals. Mexico finished second and faced Peru, the runner-up of Group A, in the quarterfinals. Chile finished third and faced Colombia, the winner of Group C, in the quarterfinals. Venezuela finished fourth in the group and was eliminated from the tournament.

Standings

Team Pld W D L GF GA GD Pts
 Brazil 3 3 0 0 10 1 +9 9
 Mexico 3 2 0 1 5 3 +2 6
 Chile 3 1 0 2 3 2 +1 3
 Venezuela 3 0 0 3 1 13 −12 0
Source:

Teams that advanced to the quarterfinals

Matches

Chile v Mexico

Chile 0–1 Mexico
Report Hernández 59'
Attendance: 22,000
Chile
Mexico
GK1Marcelo Ramírez
DF13Jorge Vargas
DF3Miguel Ramírez
DF4Francisco Rojas
DF6Pedro ReyesYellow card 21'
MF7Nelson Parraguez
MF8Clarence AcuñaYellow card 20'downward-facing red arrow 74'
MF19Esteban Valenciadownward-facing red arrow 80'
FW22David Pizarrodownward-facing red arrow 65'
FW9Iván Zamorano
FW11Marcelo Salas
Substitutions:
MF20Fabián Estayupward-facing green arrow 65'
FW18Pedro Gonzálezupward-facing green arrow 74'
MF2Raúl Palaciosupward-facing green arrow 80'
Manager:
Uruguay Nelson Acosta
GK1Jorge Campos
DF13Pável Pardo
DF4Rafael Márquez
DF2Claudio Suárez
DF18Salvador Carmona
MF6Raúl Lara
MF19Miguel ZepedaYellow card 25'downward-facing red arrow 46'
MF8Alberto García Aspedownward-facing red arrow 78'
MF7Ramón RamírezYellow card 74'
FW15Luis Hernández
FW10Cuauhtémoc Blancodownward-facing red arrow 80'
Substitutions:
FW17Francisco Palenciaupward-facing green arrow 46'
DF3Joel Sánchezupward-facing green arrow 78'
MF9Paulo Chávezupward-facing green arrow 80'
Manager:
Manuel Lapuente

Brazil v Venezuela

Brazil 7–0 Venezuela
Ronaldo 28', 62'
Emerson 40'
Amoroso 54', 81'
Ronaldinho 74'
Rivaldo 82'		 Report
Attendance: 22,000
Referee: Bonifacio Núñez (Paraguay)
Brazil
Venezuela
GK1Dida
DF2CafuYellow card 27'downward-facing red arrow 77'
DF3Odvan
DF4Antônio Carlos
DF6Roberto Carlosdownward-facing red arrow 75'
MF5EmersonYellow card 69'
MF8Vampeta
MF10Rivaldo
MF11Alexdownward-facing red arrow 70'
FW7Márcio Amoroso
FW9Ronaldo
Substitutions:
FW21Ronaldinhoupward-facing green arrow 70'
DF16Serginhoupward-facing green arrow 75'
DF13Evanílsonupward-facing green arrow 77'
Manager:
Vanderlei Luxemburgo
GK1Renny Vega
DF4David McIntoshdownward-facing red arrow 45'
DF2Rolando Álvarez
DF6José Manuel Rey
DF3Jorge Rojas
MF8Edson Tortolero
MF21José VeraYellow card 31'downward-facing red arrow 65'
MF5Héctor Bidoglio
MF10Gabriel UrdanetaYellow card 90'
FW7Daniel Noriega
FW11Félix HernándezYellow card 40'downward-facing red arrow 60'
Substitutions:
MF14Leopoldo Jiménezupward-facing green arrow 45'
FW22Ruberth Moránupward-facing green arrow 60'
MF16José Dunoupward-facing green arrow 65'
Manager:
Argentina José Omar Pastoriza

Brazil v Mexico

Brazil 2–1 Mexico
Amoroso 20'
Alex 45'		 Report Terrazas 74'
Attendance: 22,000
Brazil
Mexico
GK1Dida
DF2Cafu
DF3OdvanYellow card 21'
DF4Antônio CarlosYellow card 86'
DF6Roberto Carlos
MF5EmersonYellow card 74'
MF8Vampeta
MF11Alexdownward-facing red arrow 78'
FW10RivaldoRed card 82'
FW7Márcio Amorosodownward-facing red arrow 80'
FW9Ronaldodownward-facing red arrow 90'
Substitutions:
MF18Flávio Conceiçãoupward-facing green arrow 78'
FW21Ronaldinhoupward-facing green arrow 80'
DF15João Carlosupward-facing green arrow 90'
Manager:
Vanderlei Luxemburgo
GK1Jorge Campos
DF13Pável Pardo
DF2Claudio Suárez
DF3Joel Sánchez
DF18Salvador Carmona
MF9Paulo Chávezdownward-facing red arrow 46'
MF6Raúl Lara
MF8Alberto García Aspe Yellow card 14'downward-facing red arrow 46'
MF20Rafael Garcíadownward-facing red arrow 64'
FW15Luis Hernández
FW10Cuauhtémoc Blanco
Substitutions:
MF5Gerardo Torradoupward-facing green arrow 46'
DF14Isaac Terrazasupward-facing green arrow 46'
MF11Daniel Osornoupward-facing green arrow 64'
Manager:
Manuel Lapuente

Chile v Venezuela

Chile 3–0 Venezuela
Zamorano 5'
Sierra 21'
Tortolero 66' (o.g.)		 Report
Attendance: 22,000
Referee: Juan Luna (Bolivia)
Chile
Venezuela
GK1Marcelo Ramírez
DF13Jorge VargasYellow card Yellow-red card 39'
DF6Pedro Reyes
DF3Miguel Ramírez
MF2Raúl Palacios
MF8Clarence Acuña
MF16Mauricio Aros
MF20Fabián Estay
MF10José Luis Sierradownward-facing red arrow 46'
FW9Iván Zamoranodownward-facing red arrow 75'
FW11Marcelo SalasYellow card 38' Red card 69'
Substitutions:
MF7Nelson Parraguezupward-facing green arrow 46'
FW18Pedro Gonzálezupward-facing green arrow 75'
Manager:
Uruguay Nelson Acosta
GK1Renny Vega
DF14Leopoldo Jiménez
DF2Rolando ÁlvarezRed card 18'
DF6José Manuel ReyYellow card 40'
DF17Miguel Echenausi
MF8Edson Tortolero
MF21José Vera
MF5Héctor Bidoglio
MF10Gabriel Urdanetadownward-facing red arrow 60'
FW22Ruberth Morándownward-facing red arrow 55'
FW7Daniel Noriega
Substitutions:
FW9Juan GarcíaYellow card 58'upward-facing green arrow 55'
FW11Félix Hernándezupward-facing green arrow 60'
Manager:
Argentina José Omar Pastoriza

Mexico v Venezuela

Mexico 3–1 Venezuela
Blanco 21', 39'
Osorno 29'		 Report Urdaneta 72'
Attendance: 18,000
Referee: Bonifacio Núñez (Paraguay)
Mexico
Venezuela
GK22Adolfo RíosYellow card 66'
DF3Joel Sánchez
DF21Sergio AlmaguerYellow card 14'downward-facing red arrow 46'
DF9Paulo Chávezdownward-facing red arrow 63'
DF18Salvador Carmona
MF20Rafael García
MF5Gerardo TorradoYellow card 3'downward-facing red arrow 46'
MF6Raúl Lara
MF17Francisco Palencia
FW11Daniel OsornoYellow card 87'
FW10Cuauhtémoc Blanco Red card 83'
Substitutions:
DF2Claudio Suárezupward-facing green arrow 46'
MF15Salvador Cabreraupward-facing green arrow 46'
DF14Isaac Terrazasupward-facing green arrow 63'
Manager:
Manuel Lapuente
GK12Manuel Sanhouse
DF5Héctor Bidoglio
DF6José Manuel Rey
DF14Leopoldo Jiménez Yellow card 49'
DF15Miguel Mea Vitali
MF16José Dunodownward-facing red arrow 58'
MF17Miguel Echenausi
MF21José Vera
MF10Gabriel Urdaneta
FW22Ruberth Morándownward-facing red arrow 77'
FW7Daniel Noriegadownward-facing red arrow 62'
Substitutions:
MF19Juan Arangoupward-facing green arrow 58'
FW20Cristian Cásseresupward-facing green arrow 62'
FW9Juan Garcíaupward-facing green arrow 77'
Manager:
Argentina José Omar Pastoriza

Brazil v Chile

Brazil
Chile
GK1Dida
DF13EvanílsonYellow card 55'
DF3Odvan
DF15João Carlos
DF6Roberto Carlos
MF18Flávio Conceição
MF8Vampetadownward-facing red arrow 16'
MF22Zé Roberto
MF11Alexdownward-facing red arrow 73'
FW9Ronaldo
FW7Márcio Amorosodownward-facing red arrow 46'
Substitutions:
MF19Betoupward-facing green arrow 16'
FW21Ronaldinhoupward-facing green arrow 46'
FW20ChristianYellow card 76'upward-facing green arrow 73'
Manager:
Vanderlei Luxemburgo
GK1Marcelo RamírezYellow card 13'
DF15Moisés Villarroeldownward-facing red arrow 70'
DF21Pablo ContrerasYellow card 33'
DF3Miguel Ramírez
DF5Javier Margas
MF4Francisco Rojas
MF7Nelson Parraguezdownward-facing red arrow 46'
MF14Roberto Cartes
MF10José Luis SierraYellow card 71'
FW9Iván ZamoranoYellow card 33'downward-facing red arrow 46'
FW18Pedro GonzálezYellow card 55'
Substitutions:
MF2Raúl Palaciosupward-facing green arrow 46'
FW17Claudio Núñezupward-facing green arrow 46'
MF16Mauricio Arosupward-facing green arrow 70'
Manager:
Uruguay Nelson Acosta
  1. ↑ Match stopped by referee after 85 minutes due to heavy fog and abandoned after few minutes of waiting, with score declared final.
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