| Germanite | |
|---|---|
|  Germanite, probably from the Tsumeb Mine, Oshikoto Region, Namibia. | |
| General | |
| Category | Sulfide mineral | 
| Formula (repeating unit) | Cu26Ge4Fe4S32[1] | 
| IMA symbol | Ger[2] | 
| Strunz classification | 2.CB.30 | 
| Dana classification | 2.9.4.2 | 
| Crystal system | Isometric | 
| Crystal class | Hextetrahedral (43m) H-M symbol: (4 3m) | 
| Space group | P43n | 
| Identification | |
| Color | Reddish grey tarnishing to dark brown | 
| Crystal habit | Usually massive; rarely as minute cubic crystals | 
| Cleavage | None | 
| Tenacity | Brittle | 
| Mohs scale hardness | 4 | 
| Luster | Metallic | 
| Streak | Dark grey to black | 
| Diaphaneity | Opaque | 
| Specific gravity | 4.4 to 4.6 | 
| Other characteristics | Cell data: a = 10.585 Å Z = 1[3] | 
| References | [4][5] | 
Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content.[3] It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite.[6] Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities.[3]
Its type locality is the Tsumeb Mine in Namibia where it occurs in a hydrothermal polymetallic ore deposit in dolomite in association with renierite, pyrite, tennantite, enargite, galena, sphalerite, digenite, bornite and chalcopyrite.[5] It has also been reported from Argentina, Armenia, Bulgaria, Cuba, Democratic Republic of Congo (Zaire), Finland, France, Greece, Japan, Republic of Congo (Brazzaville), Russia and the United States.[3]
| X-Ray Powder Diffraction[7] | ||||||||
|---|---|---|---|---|---|---|---|---|
| d spacing | 3.05 | 2.65 | 1.87 | 1.60 | 1.32 | 1.21 | 1.08 | 1.02 | 
| relative intensity | 10 | 1 | 7 | 4 | 1 | 2 | 2 | 1 | 
References
- ↑ American Mineralogist (1984) 69:943-947
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- 1 2 3 4 http://www.mindat.org/min-1681.html Mindat.org
- ↑ http://webmineral.com/data/Germanite.shtml Webmineral
- 1 2 http://rruff.geo.arizona.edu/doclib/hom/germanite.pdf Handbook of Mineralogy
- ↑ U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries http://minerals.usgs.gov/minerals/pubs/commodity/germanium/
- ↑ Dana's New Mineralogy, 8th edition, Gaines et al., Wiley
